![]() ![]() ![]() Coord Chem Rev 393:48–78īalach J, Linnemann J, Jaumann T, Giebeler L (2018) Metal-based nanostructured materials for advanced lithium-sulfur batteries. Shrivastav V, Sundriyal S, Goel P, Kaur H, Tuteja SK, Vikrant K et al (2019) Metal-organic frameworks (MOFs) and their composites as electrodes for lithium battery applications: Novel means for alternative energy storage. Liu B, Bo R, Taheri M, Di Bernardo I, Motta N, Chen H et al (2019) Metal-organic frameworks/conducting polymer hydrogel integrated three-dimensional free-standing monoliths as ultrahigh loading Li-S battery electrodes. Zhong Y, Xu X, Liu Y, Wang W, Shao Z (2018) Recent progress in metal–organic frameworks for lithium–sulfur batteries. Yang X, Yan N, Zhou W, Zhang H, Li X, Zhang H (2015) Sulfur embedded in one-dimensional French fries-like hierarchical porous carbon derived from a metal–organic framework for high performance lithium–sulfur batteries. Chem Eng J 369:77–86įeng Y, Zhang Y, Du G, Zhang J, Liu M, Qu X (2018) Li2S–Embedded copper metal–organic framework cathode with superior electrochemical performance for Li–S batteries. Yang Y, Wang S, Zhang L, Deng Y, Xu H, Qin X et al (2019) CoS-interposed and Ketjen black-embedded carbon nanofiber framework as a separator modulation for high performance Li-S batteries. Leng S, Chen C, Liu J, Wang S, Yang J, Shan S et al (2019) Optimized sulfur-loading in nitrogen-doped porous carbon for high-capacity cathode of lithium–sulfur batteries. Xu J, Zhang W, Chen Y, Fan H, Su D, Wang G (2018) MOF-derived porous nanododecahedra wrapped with reduced graphene oxide as a high capacity cathode for lithium–sulfur batteries. Pu Y, Wu W, Liu J, Liu T, Ding F, Zhang J et al (2018) A defective MOF architecture threaded by interlaced carbon nanotubes for high-cycling lithium-sulfur batteries. Zhang H, Zhao W, Zou M, Wang Y, Chen Y, Xu L et al (2018) 3D, Mutually embedded nanotube hybrid networks for high-performance lithium-sulfur batteries. Jie L (2019) Hierarchically constructed TiO 2 spheres as efficient polysulfide barrier for high-performance Li-S battery. Li J, Zhang L, Qin F, Hong B, Xiang Q, Zhang K et al (2019) ZrO(NO 3)( 2) as a functional additive to suppress the diffusion of polysulfides in lithium - sulfur batteries. Hong X-J, Tang X-Y, Wei Q, Song C-L, Wang S-Y, Dong R-F et al (2018) Efficient encapsulation of small S 2– 4 molecules in MOF-derived flowerlike nitrogen-doped microporous carbon nanosheets for high-performance Li-S batteries. Zhou X, Tian J, Hu J, Li C (2018) High rate magnesium-sulfur battery with improved cyclability based on metal-organic framework derivative carbon host. Liu M, Ye F, Li W, Li H, Zhang Y (2016) Chemical routes toward long-lasting lithium/sulfur cells. Ionics 26:5435–5443Ĭho C-S, Chang J-Y, Li C-C (2020) Highly symmetric gigaporous carbon microsphere as conductive host for sulfur to achieve high areal capacity for lithium-sulfur batteries. Liu C, Xiang M, Xiao J, Ma S, Zeng Y, Li X et al (2020) Hollow V 2O 5 nanospheres wrapped by activated carbon to confine polysulfides for lithium sulfur battery. Seh ZW, Wang H, Hsu P-C, Zhang Q, Li W, Zheng G et al (2014) Facile synthesis of Li 2S–polypyrrole composite structures for high-performance Li 2S cathodes. Qi W, Li Y, Li H, Wayne SW, Lin X (2019) The development and numerical verification of a compromised real time optimal control algorithm for hybrid electric vehicle. Jiang H, Liu X-C, Wu Y, Shu Y, Gong X, Ke F-S et al (2018) Metal-organic frameworks for high charge-discharge rates in lithium-sulfur batteries. This work offers a new strategy for constructing the MOFs-based cathode materials for Li–S batteries with high performance. The initial discharge capacity of the can reach as high as 1400 mAh∙g −1 and maintain a capacity of about 840 mAh∙g −1 after 100 charge–discharge cycles at 0.1 C, the coulombic efficiency approaches 100%. Based on it, we used the indium-based MOF-CPM-200 as a carrier, combined with the conductive multi-walled carbon nanotubes (CNT) and sulfur to construct the composite cathode material of The unique composite structure for cathode materials of Li–S batteries can inhibit the “shuttle effect” and enhance conductivity. With strong bonding ability to sulfur, indium-based MOFs, in which the indium (In) shows the Lewis acid character, can form the stable chemical bonds of In-S. However, their low binding energy with sulfur and poor absorbability of polysulfides leads to the “shuttle effect,” reducing the stability of MOFs. Metal–organic frameworks (MOFs) exhibit great potential for lithium-sulfur (Li–S) batteries because of their unique characteristics such as the high surface area, the precise structure, and the tunable porous environment.
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